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Rare-earth separation based on the differences of ionic magnetic moment via quasi-liquid strategy

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1584-1594 doi: 10.1007/s11705-022-2189-4

摘要: The separation of rare earth elements is particularly difficult due to their similar physicochemical properties. Based on the tiny differences of ionic radius, solvent extraction has been developed as the “mass method” in industry with hundreds of stages, extremely intensive chemical consumption and large capital investments. The differences of the ionic magnetic moment among rare earths are greater than that of ionic radius. Herein, a novel method based on the large ionic magnetic moment differences of rare earth elements was proposed to promote the separation efficiency. Rare earths were firstly dissolved in the ionic liquid, then the ordering degree of them was improved with the Z-bond effect, and finally the magnetic moment differences between paramagnetic and diamagnetic rare earths in quasi-liquid system were enhanced. Taking the separation of Er/Y, Ho/Y and Er/Ho as examples, the results showed that Er(III) and Ho(III) containing ionic liquids had obvious magnetic response, while ionic liquids containing Y(III) had no response. The separation factors of Er/Y and Ho/Y were achieved at 9.0 and 28.82, respectively. Magnetic separation via quasi-liquid system strategy provides a possibility of the novel, green, and efficient method for rare earth separation.

关键词: rare earth element     different magnetic moment     magnetic separation     ionic liquid    

Characteristics of metal magnetic memory signals of different steels under static tension

Yiliang ZHANG, Ruibin GOU, Jimin LI, Gongtian SHEN,

《机械工程前沿(英文)》 2010年 第5卷 第2期   页码 226-232 doi: 10.1007/s11465-010-0012-2

摘要: To study the characteristics of metal magnetic memory (MMM) signals of different steels during tensile test, static tension tests were applied to 30 pieces of Q235 and 16MnR base metal and welded specimens. During the various deformation periods, MMM signals are tested, and micrometallographic is observed. Furthermore, the derivative of magnetic intensity (d/d) is analyzed by mathematical and statistical methods to study the macro and micro corresponding relationships and difference among magnetic signals. Results show that despite the different magnetic intensity () curves of different materials, their d/d patterns in the yielding and necking stages are the same; welded specimens have the similar magnetic signal curves with their base metal, and the welded structure does not interfere with its distribution; different materials have their unique zero point (=0) before being fractured, which is independent of the fracture location; there is a direct relationship between the intragranular slip and the changes of magnetic signals, which indicates the uneven plastic deformation.

关键词: metal magnetic memory (MMM)     magnetic intensity (Hp)     static tension     weld    

Instantaneous deflection of light-weight concrete slabs

Behnam VAKHSHOURI, Shami NEJADI

《结构与土木工程前沿(英文)》 2017年 第11卷 第4期   页码 412-423 doi: 10.1007/s11709-017-0416-8

摘要: Construction loading before the age of 28 d can have the most significant effects on the slabs, especially for multi-story structures. The changing properties of the young concrete complicate the prediction of serviceability design requirements also. An experimental investigation is performed on four simply supported Light-Weight Concrete (LWC) one-way slabs subjected to immediate loading at 14 d. Effects of aggregate type, loading levels and cracking moment together with the influences of ultimate moment capacity and service moment on the instantaneous deflection of slabs are studied. Comparison of the obtained results with predictions of existing models in the literature shows considerable differences between the recorded and estimated instantaneous deflection of LWC slabs. Based on sensitivity analysis of the effective parameters, a new equation is proposed and verified to predict the instantaneous deflection of LWC slabs subjected to loading at the age of 14 d.

关键词: instantaneous deflection     light-weight concrete     expanded polystyrene     effective moment of inertia     cracking moment     moment capacity     service moment    

Estimating moment capacity of ferrocement members using self-evolving network

Abdussamad ISMAIL

《结构与土木工程前沿(英文)》 2019年 第13卷 第4期   页码 926-936 doi: 10.1007/s11709-019-0527-5

摘要: In this paper, an empirical model based on self-evolving neural network is proposed for predicting the flexural behavior of ferrocement elements. The model is meant to serve as a simple but reliable tool for estimating the moment capacity of ferrocement members. The proposed model is trained and validated using experimental data obtained from the literature. The data consists of information regarding flexural tests on ferrocement specimens which include moment capacity and cross-sectional dimensions of specimens, concrete cube compressive strength, tensile strength and volume fraction of wire mesh. Comparisons of predictions of the proposed models with experimental data indicated that the models are capable of accurately estimating the moment capacity of ferrocement members. The proposed models also make better predictions compared to methods such as the plastic analysis method and the mechanism approach. Further comparisons with other data mining techniques including the back-propagation network, the adaptive spline, and the Kriging regression models indicated that the proposed models are superior in terms prediction accuracy despite being much simpler models. The performance of the proposed models was also found to be comparable to the GEP-based surrogate model.

关键词: ferrocement     moment capacity     self-evolving neural network    

Shaking-moment balancing of mechanisms with principal vectors and momentum

V. van der WIJK

《机械工程前沿(英文)》 2013年 第8卷 第1期   页码 10-16 doi: 10.1007/s11465-013-0359-2

摘要:

The design of shaking-moment-balanced linkages still is challenging. Considering moment balance in the very beginning of the design process of mechanisms is important for finding applicable solutions. For this purpose, the method of principal vectors is investigated, showing a compact notation of the angular momentum with respect to the center of mass. The moment balance conditions are derived for three elements in series from which balance solutions are synthesized and illustrated. From the application for moment balancing of a 4R four-bar linkage it is shown that the moment balancing of closed kinematic chains remains challenging.

关键词: shaking-moment balancing     principal vector linkage     angular momentum    

Initial stiffness and moment resistance of reinforced joint with end-plate connection

Sufang WANG, Yiyi CHEN,

《结构与土木工程前沿(英文)》 2009年 第3卷 第4期   页码 345-351 doi: 10.1007/s11709-009-0054-x

摘要: In beam-to-column joint with bolted end-plate connection, the structural details of column flange reinforced by backing plate and column web panel reinforced by supplementary plate are analyzed. The joint is divided into some basic components, and the initial stiffness of each component is obtained. Especially, the initial stiffness of reinforced components is drawn by theoretical model and finite element analysis. The initial stiffness of reinforced joint can be obtained by assembling the initial stiffness of each component. The design moment resistance of column flange reinforced by backing plate is deduced based on yield line method, and the design moment resistances of other components are deduced based on present codes. The design moment resistance of the reinforced joint is then determined by the minimum of the design moment resistances of all components. By comparison with the results of finite element calculation, it is verified that the method to calculate the initial stiffness of reinforced joint is accurate enough to be used to estimate the rigid behavior of the joint and to make parametric study.

关键词: steel structure     end-plate connection     backing plate     supplementary web plate     initial stiffness     moment resistance    

Improved prediction of pile bending moment and deflection due to adjacent braced excavation

《结构与土木工程前沿(英文)》 doi: 10.1007/s11709-023-0961-2

摘要: Deep excavations in dense urban areas have caused damage to nearby existing structures in numerous past construction cases. Proper assessment is crucial in the initial design stages. This study develops equations to predict the existing pile bending moment and deflection produced by adjacent braced excavations. Influential parameters (i.e., the excavation geometry, diaphragm wall thickness, pile geometry, strength and small-strain stiffness of the soil, and soft clay thickness) were considered and employed in the developed equations. It is practically unfeasible to obtain measurement data; hence, artificial data for the bending moment and deflection of existing piles were produced from well-calibrated numerical analyses of hypothetical cases, using the three-dimensional finite element method. The developed equations were established through a multiple linear regression analysis of the artificial data, using the transformation technique. In addition, the three-dimensional nature of the excavation work was characterized by considering the excavation corner effect, using the plane strain ratio parameter. The estimation results of the developed equations can provide satisfactory pile bending moment and deflection data and are more accurate than those found in previous studies.

关键词: pile responses     excavation     prediction     deflection     bending moments    

Modeling and analysis of magnetic dipoles in weak magnetic field

WANG Zhaoxia, ZHANG Weimin, LIU Hongguang

《机械工程前沿(英文)》 2008年 第3卷 第2期   页码 222-225 doi: 10.1007/s11465-008-0028-z

摘要: The magnetic leakage field distribution resulting from linear defects of a tube sample in the geomagnetic field is modeled according to the magnetic dipole theory. The formula to compute the normal component of the weak magnetic field is deduced based on the spatial distribution of the magnetic dipole. The shape and characteristics of the zero line (an important criterion for magnetic memory testing) of the normal field is analyzed under different longitudinal magnetizations. Results show that the characteristics of the zero line should be considered when the metal magnetic memory testing method is used to find and locate the defect.

关键词: geomagnetic     theory     important criterion     magnetic leakage     normal component    

High-order moment methods for LRFD including random variables with unknown probability distributions

Zhao-Hui LU, Yan-Gang ZHAO, Zhi-Wu YU

《结构与土木工程前沿(英文)》 2013年 第7卷 第3期   页码 288-295 doi: 10.1007/s11709-013-0210-1

摘要: The reliability-based load and resistance factors design (LRFD) has been widely used in the structural design codes. In almost all of the current reliability methods for the determination of the load and resistance factors, the basic random variables are assumed to have known probability distributions. However, in reality, the probability distributions of some of the basic random variables are often unknown due to the lack of statistical data. In this paper, the high-order moment methods for LRFD including random variables with unknown probability distributions are proposed. From the investigation of the present paper, it can be concluded that: 1) The load and resistance factors can be determined even when the probability distributions of the basic random variables are unknown; 2) The present method is convenient and more effective in estimating the load and resistance factors in practical engineering since it needs neither the iterative computation of derivatives nor any design points; 3) In the applicable range of the high-order moment method, although the load and resistance factors obtained by the proposed method may be different from those obtained by first order reliability method (FORM), the target mean resistances obtained by both methods are essentially the same.

关键词: high-order moment methods     applicable range     load and resistance factors     target mean resistance    

Damage identification in connections of moment frames using time domain responses and an optimization

《结构与土木工程前沿(英文)》 2021年 第15卷 第4期   页码 851-866 doi: 10.1007/s11709-021-0739-3

摘要: Damage is defined as changes to the material and/or geometric properties of a structural system, comprising changes to the boundary conditions and system connectivity, adversely affecting the system’s performance. Inspecting the elements of structures, particularly critical components, is vital to evaluate the structural lifespan and safety. In this study, an optimization-based method for joint damage identification of moment frames using the time-domain responses is introduced. The beam-to-column connection in a metallic moment frame structure is modeled by a zero-length rotational spring at both ends of the beam element. For each connection, an end-fixity factor is specified, which changes between 0 and 1. Then, the problem of joint damage identification is converted to a standard optimization problem. An objective function is defined using the nodal point accelerations extracted from the damaged structure and an analytical model of the structure in which the nodal accelerations are obtained using the Newmark procedure. The optimization problem is solved by an improved differential evolution algorithm (IDEA) for identifying the location and severity of the damage. To assess the capability of the proposed method, two numerical examples via different damage scenarios are considered. Then, a comparison between the proposed method and the existing damage identification method is provided. The outcomes reveal the high efficiency of the proposed method for finding the severity and location of joint damage considering noise effects.

关键词: damage identification     beam-to-column connection     time-domain response     optimization    

Estimation of load and resistance factors using the third-moment method based on the 3P-lognormal distribution

Yan-Gang ZHAO, Zhao-Hui LU

《结构与土木工程前沿(英文)》 2011年 第5卷 第3期   页码 315-322 doi: 10.1007/s11709-011-0117-7

摘要: Load and resistance factors are generally obtained using the first order reliability method (FORM) in which the design point should be determined and derivative-based iterations used. In this article, the third-moment reliability index, based on the three-parameter lognormal (3P-lognormal) distribution, is investigated. A simple method based on the third-moment method for estimating load and resistance factors is then proposed, and a simple formula for the target mean resistance is also presented to avoid iterative computations. Unlike the currently used method, the proposed method can be used to determine load and resistance factors, even when the probability density functions (PDFs) of the basic random variables are not available. Moreover, the proposed method does not require the iterative computation of derivatives or any design points. Thus, the method provides a more convenient and effective way to estimate load and resistance factors in practical engineering applications. Numerical examples are presented to demonstrate the advantages of the proposed third moment method for determining load and resistance factors.

关键词: load and resistance factors     third-moment method     three-parameter lognormal (3P-lognormal) distribution     target mean resistance     simple formula    

Seismic performance of moment resisting steel frame subjected to earthquake excitations

Fadzli M. NAZRI, Pang Yew KEN

《结构与土木工程前沿(英文)》 2014年 第8卷 第1期   页码 19-25 doi: 10.1007/s11709-014-0240-3

摘要: This study presents static and dynamic assessments on the steel structures. Pushover analysis (POA) and incremental dynamic analysis (IDA) were run on moment resisting steel frames. The IDA study involves successive scaling and application of each accelerogram followed by assessment of the maximum response. Steel frames are subjected to nonlinear inelastic time history analysis for 14 different scaled ground motions, 7 near field and 7 far field. The results obtained from POA on the 3, 6 and 9 storey steel frames show consistent results for both uniform and triangular lateral loading. Uniform loading shows that the steel frames exhibits higher base shear than the triangular loading. The IDA results show that the far field ground motions has caused all steel frame design within the research to collapse while near field ground motion only caused some steel frames to collapse. The POA can be used to estimate the performance-based-seismic-design (PBSD) limit states of the steel frames with consistency while the IDA seems to be quite inconsistent. It is concluded that the POA can be consistently used to estimate the limit states of steel frames while limit state estimations from IDA requires carefully selected ground motions with considerations of important parameters.

关键词: incremental dynamic analysis (IDA)     pushover analysis     performance-based seismic design    

An innovative model for predicting the displacement and rotation of column-tree moment connection under

Mohammad Ali NAGHSH, Aydin SHISHEGARAN, Behnam KARAMI, Timon RABCZUK, Arshia SHISHEGARAN, Hamed TAGHAVIZADEH, Mehdi MORADI

《结构与土木工程前沿(英文)》 2021年 第15卷 第1期   页码 194-212 doi: 10.1007/s11709-020-0688-2

摘要: In this study, we carried out nonlinear finite element simulations to predict the performance of a column-tree moment connection (CTMC) under fire and static loads. We also conducted a detailed parameter study based on five input variables, including the applied temperature, number of flange bolts, number of web bolts, length of the beam, and applied static loads. The first variable is changed among seven levels, whereas the other variables are changed among three levels. Employing the Taguchi method for variables 2–5 and their levels, 9 samples were designed for the parameter study, where each sample was exposed to 7 different temperatures yielding 63 outputs. The related variables for each output are imported for the training and testing of different surrogate models. These surrogate models include a multiple linear regression (MLR), multiple Ln equation regression (MLnER), an adaptive network-based fuzzy inference system (ANFIS), and gene expression programming (GEP). 44 samples were used for training randomly while the remaining samples were employed for testing. We show that GEP outperforms MLR, MLnER, and ANFIS. The results indicate that the rotation and deflection of the CTMC depend on the temperature. In addition, the fire resistance increases with a decrease in the beam length; thus, a shorter beam can increase the fire resistance of the building. The numbers of flanges and web bolts slightly affect the rotation and displacement of the CTMCs at temperatures of above 400°C.

关键词: column-tree moment connection     Finite element model     parametric study     fire     regression models     gene expression programming    

Continuous size fractionation of magnetic nanoparticles by using simulated moving bed chromatography

Carsten-Rene Arlt, Dominik Brekel, Stefan Neumann, David Rafaja, Matthias Franzreb

《化学科学与工程前沿(英文)》 2021年 第15卷 第5期   页码 1346-1355 doi: 10.1007/s11705-021-2040-3

摘要: The size fractionation of magnetic nanoparticles is a technical problem, which until today can only be solved with great effort. Nevertheless, there is an important demand for nanoparticles with sharp size distributions, for example for medical technology or sensor technology. Using magnetic chromatography, we show a promising method for fractionation of magnetic nanoparticles with respect to their size and/or magnetic properties. This was achieved by passing magnetic nanoparticles through a packed bed of fine steel spheres with which they interact magnetically because single domain ferro-/ferrimagnetic nanoparticles show a spontaneous magnetization. Since the strength of this interaction is related to particle size, the principle is suitable for size fractionation. This concept was transferred into a continuous process in this work using a so-called simulated moving bed chromatography. Applying a suspension of magnetic nanoparticles within a size range from 20 to 120 nm, the process showed a separation sharpness of up to 0.52 with recovery rates of 100%. The continuous feed stream of magnetic nanoparticles could be fractionated with a space-time-yield of up to 5 mg/(L∙min). Due to the easy scalability of continuous chromatography, the process is a promising approach for the efficient fractionation of industrially relevant amounts of magnetic nanoparticles.

关键词: magnetic chromatography     simulated moving bed chromatography     magnetic nanoparticles     size fractionation    

Magnetostriction varieties and stress relief caused by pulsed magnetic field

Zhipeng CAI, Xinjie DUAN, Jian LIN, Haiyan ZHAO

《机械工程前沿(英文)》 2011年 第6卷 第3期   页码 354-358 doi: 10.1007/s11465-011-0123-4

摘要:

Magnetostriction is investigated to evaluate the stress relief caused by pulsed magnetic field treatment, because this physical property is closely associated with residual stress. Magnetostriction of different stressed samples is measured in this paper. The stress variations caused by pulsed magnetic treatment are also compared. It is found that magnetostriction variations are closely associated with stress changes. Thermodynamic potential is used to find the relationship between them. Based on several assumptions, we find that the product of magnetostriction amplitude and stress magnitude is nearly a constant during magnetic field treatment, which is valuable for stress relief evaluation and optimizing processing parameters. This conclusion is testified by stress measurements, and the calculated values are in accordance with the experiment results.

关键词: magnetostriction     pulsed magnetic field treatment     stress relief    

标题 作者 时间 类型 操作

Rare-earth separation based on the differences of ionic magnetic moment via quasi-liquid strategy

期刊论文

Characteristics of metal magnetic memory signals of different steels under static tension

Yiliang ZHANG, Ruibin GOU, Jimin LI, Gongtian SHEN,

期刊论文

Instantaneous deflection of light-weight concrete slabs

Behnam VAKHSHOURI, Shami NEJADI

期刊论文

Estimating moment capacity of ferrocement members using self-evolving network

Abdussamad ISMAIL

期刊论文

Shaking-moment balancing of mechanisms with principal vectors and momentum

V. van der WIJK

期刊论文

Initial stiffness and moment resistance of reinforced joint with end-plate connection

Sufang WANG, Yiyi CHEN,

期刊论文

Improved prediction of pile bending moment and deflection due to adjacent braced excavation

期刊论文

Modeling and analysis of magnetic dipoles in weak magnetic field

WANG Zhaoxia, ZHANG Weimin, LIU Hongguang

期刊论文

High-order moment methods for LRFD including random variables with unknown probability distributions

Zhao-Hui LU, Yan-Gang ZHAO, Zhi-Wu YU

期刊论文

Damage identification in connections of moment frames using time domain responses and an optimization

期刊论文

Estimation of load and resistance factors using the third-moment method based on the 3P-lognormal distribution

Yan-Gang ZHAO, Zhao-Hui LU

期刊论文

Seismic performance of moment resisting steel frame subjected to earthquake excitations

Fadzli M. NAZRI, Pang Yew KEN

期刊论文

An innovative model for predicting the displacement and rotation of column-tree moment connection under

Mohammad Ali NAGHSH, Aydin SHISHEGARAN, Behnam KARAMI, Timon RABCZUK, Arshia SHISHEGARAN, Hamed TAGHAVIZADEH, Mehdi MORADI

期刊论文

Continuous size fractionation of magnetic nanoparticles by using simulated moving bed chromatography

Carsten-Rene Arlt, Dominik Brekel, Stefan Neumann, David Rafaja, Matthias Franzreb

期刊论文

Magnetostriction varieties and stress relief caused by pulsed magnetic field

Zhipeng CAI, Xinjie DUAN, Jian LIN, Haiyan ZHAO

期刊论文